The Art of Writing Reasonable Organic Reaction Mechanisms (4th reprinting)
R B Grossman
2003 (reprint 2007)
Intended for students of intermediate organic chemistry, this text shows how to write a reasonable
mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms
and the conditions under which the reaction is executed, rather than by the overall reaction as is the case
in most textbooks. The treatment emphasizes unifying principles, showing how common mechanisms link
seemingly disparate reactions. Each chapter discusses common mechanistic pathways and suggests practical
tips for drawing them. Worked problems are included in the discussion of each mechanism, and "common error
alerts" are scattered throughout the text to warn readers about pitfalls and misconceptions that bedevil students.
Each chapter is capped by a large problem set.
Hardcover 355 pp ISBN 9780387954684
The author has drawn on his own research and the current literature to ensure that appropriate
attention is given to topics across the range of modern organic chemistry. The text is unique in its
inclusion of a chapter on reactions mediated or catalyzed by transition metals, an area in which
mechanistic understanding is now essential. Relatively new topics such as olefin metathesis and
cycloaromatization are covered without giving short shrift to more traditional areas such as carbonyl
The text assumes a basic knowledge of organic chemistry. It can be used either in a formal
course or by students working on their own, and will be particularly useful for graduate students
studying for qualifying examinations. It will also be useful to students and researchers in biochemistry,
pharmacology, and inorganic chemistry.
1 The Basics.
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2 Polar Reactions under Basic Conditions.
3 Polar Reactions under Acidic Conditions.
4 Pericyclic Reactions.
5 Free-Radical Reactions.
6 Transition-Metal-Mediated and -Catalyzed
7 Mixed-Mechanism Problems.
: writing skills